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MONOCROTALINE

Product Name MONOCROTALINE
cas 315-22-0
purity 99%

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What is the MONOCROTALINE ?

MONOCROTALINE is white to light tan powder, while it's Molecular Formula is C16H23NO6. antineoplastic, insect sterilant

What is the CAS number for MONOCROTALINE ?

The CAS number of MONOCROTALINE is 315-22-0.

More information of MONOCROTALINE 315-22-0 are:

Synonyms	20-Norcrotalanan-11,15-dione,14,19-dihydro-12,13-dihydroxy-, (13a,14a)-;Monocrotaline (6CI,7CI,8CI);(-)-Monocrotaline;2H-[1,6]Dioxacycloundecino[2,3,4-gh]pyrrolizine-2,6(3H)-dione,4,5,8,10,12,13,13a,13b-octahydro-4,5-dihydroxy-3,4,5-trimethyl-,[3R-(3R,4R,5R,13aR,13bR*)]-;Monocrotalin;NSC 28693;Monocrotaline;(13-alpha,14-alpha)-14,19-Dihydro-12,13-dihydroxy-20-norcrotalanan-11,15-dione;Crotaline;
CAS?Number	315-22-0
Molecular Formula	C16H23NO6
Molecular Weight	325.362
Density	1.35 g/cm³
Melting Point	204 °C
Boiling Point	537.3 °C at 760 mmHg
Flash Point	278.7 °C
HS CODE	29399990
PSA	96.30000
LogP	-0.45470
Pka	12.21±0.60(Predicted)

What is MONOCROTALINE (315-22-0) used for?

A hepatotoxic alkaloid of the pyrrolizidine group obtained from Crotalaria retusa and C. spectabilis, the base is laevorotatory with [α]26D - 55.7° (CHCI3). It may be characterized as the hydrochloride, m.p. 184°C ldec.); [α]28D - 38.4° (H20) and the methiodide which crystallizes from MeOH with 3 moles of solvent, m.p. 205°C (dry, dec.); [α]28D + 23.4° (MeOH). Hydrolysis with boiling Ba(OHh furnishes retronecine and monocrotic acid, C7H120 3, b.p. 145-6°C/ 18 mm which is optically inactive. This acid yields a methyl ester, b.p. 94-6°Cj 18 mm, a p-bromophenacyl ester, m.p. 78°C and a 2:4-dinitrophenylhydrazone, m.p. 95-6°C. Hydrogenation in the presence of Pt02 as catalyst yields retro_x0002_necanol and monocrotalic acid, CSH120S' m.p. 181-2°C; [α]28D - 5.33° (H20) which gives a methyl ester, m.p. 79-800 C; [α]30D - 16.2° (EtOH) and a pbromophenacyl ester, m.p. 162-3°C.

InChI:InChI=1/C16H23NO6/c1-9-13(18)23-11-5-7-17-6-4-10(12(11)17)8-22-14(19)16(3,21)15(9,2)20/h4,9,11-12,20-21H,5-8H2,1-3H3/p+1/t9-,11+,12+,15+,16-/m0/s1

Articles related to MONOCROTALINE:

Article

Source

Human intestinal bacteria mediate reduction of the N-oxides of isoline and monocrotaline to the corresponding parent alkaloids

Tang, Jun,Wang, Zhengtao,Akao, Teruaki,Hattori, Masao

, p. 2027 - 2030 (2013)

TOTAL SYNTHESIS OF OPTICALLY ACTIVE MONOCROTALINE, A CARCINOGENIC PYRROLIZIDINE ALKALOID HAVING AN 11-MEMBERED DILACTONE

Niwa, Haruki,Okamoto, Osamu,Yamada, Kiyoyuki

, p. 5139 - 5142 (2007/10/02)

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